Squashfs
As root, copy filesystem.squashfs to some empty dir, e.g.:
cp /mnt/target/casper/filesystem.squashfs /data/local/dev/ubuntu cd /data/local/dev/ubuntu
Unpack the file then move it somewhere else (so you still have it as a backup):
unsquashfs filesystem.squashfs mv filesystem.squashfs /data/local/dev/ubuntu/backup.filesystem.squashfs
Go in squashfs-root, add/modify as per your taste then recreate filesystem.squashfs:
cd /data/local/dev/ubuntu mksquashfs squashfs-root filesystem.squashfs -b 1024k -comp xz -Xbcj x86 -e boot
copy the newly created filesystem.squashfs over the existing one on your USB drive, e.g.:
cp filesystem.squashfs /mnt/target/casper/filesystem.squashfs
then reboot and use your LIVE USB.
Note: the above commands are part of squashfs-tools.
http://unix.stackexchange.com/questions/80305/mounting-a-squashfs-filesystem-in-read-write